Iron Man Iron Man 2 Incredible Hulk (Hulk's campus rampage overlaps with Iron Man 2) Thor (end of Iron Man 2 overlaps with the middle-ish of Thor; Jane Foster's science partner references the experiment that created the Hulk) Captain America: The First Avenger (it can be assumed, from the post credits scene, that Nick Fury has already assembled the rest of the team; obviously if we are going in true chronological order, then you would watch the first 95% of this movie before Iron Man, and then the last bit after Thor)
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Iron Man 2
Incredible Hulk (Hulk's campus rampage overlaps with Iron Man 2)
Thor (end of Iron Man 2 overlaps with the middle-ish of Thor; Jane Foster's science partner references the experiment that created the Hulk)
Captain America: The First Avenger (it can be assumed, from the post credits scene, that Nick Fury has already assembled the rest of the team; obviously if we are going in true chronological order, then you would watch the first 95% of this movie before Iron Man, and then the last bit after Thor)